Small Molecule Activation

Articles about Small Molecule Activation

Efficient Organometallic Catalysis of Gas-Phase Olefin Hydrogenation in Solid Solvents

2 days ago by Wael Barakat and others at

Ligand Fluxionality in a Coordinatively Saturated Iron Complex Enables Selective Electrocatalytic Reduction of CO2 to Formate

4 days ago by Ayan Santra and others

Inorganic Chemistry, Catalysis

Catalytic Hydrosilylation of Carbonyl Compounds by a Germylyne Complex with a Mo≡Ge Triple Bond

6 November 2025 by Tara Dhungana and others at

Tohoku University

Organometallic Chemistry, Catalysis

Ambiphilic Reactivity and Switchable Methyl Transfer at a T-shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand

30 October 2025 by Sotirios Pavlidis and others at

Humboldt University Berlin

Inorganic Chemistry, Main Group Chemistry

Efficient, selective and low-overpotential electroreduction of CO2 into CO in water by a quaterpyridine molecular copper complex immobilized onto carbon

27 October 2025 by Mahdi Saad and others at

National Tsing Hua University

Inorganic Chemistry, Catalysis

Influence of Metal Species and Content of Fe-Ni-Poly(heptazine imides) on their Properties as Electrocatalysts for Zinc-Air Batteries

16 October 2025 by Franz Jacobi and others

Inorganic Chemistry, Energy

Metal-Metal Cooperative Oxidative H2O Addition Supported by Dihydrogen Bonding and Lewis Acid Interaction

14 October 2025 by Roland Schulz and others

Inorganic Chemistry, Catalysis

Stereofacial Assembly of Engineered Multi-Chiral Aziridines via B/Si Ylide Insertion

6 October 2025 by Elena Fernández and others

Organic Chemistry, Inorganic Chemistry

A Crystalline Phosphorus-Substituted Borinium Cation: Double Dihydrogen Activation by an Ambiphilic Inorganic Allene

6 October 2025 by Anna Ordyszewska-Lach and others

Inorganic Chemistry, Frustrated Lewis Pairs

Alkane Coordination by a Neutral, Lewis Acidic Magnesium Complex

26 September 2025 by Jeremy Mullins and others at

University of Melbourne

Inorganic Chemistry, Organometallic Chemistry

Prospects for forming C–N bonds from dinitrogen

25 September 2025 by Nereida Hidalgo and others

Inorganic Chemistry, Catalysis

Isolation and Cycloaddition Reactions of a Stable Boraketene

23 September 2025 by Yannick Konrad and others

Inorganic Chemistry, Main Group Chemistry

N-centered, yet Stable: an Electronic Structure Investigation of FLP-type Stabilized N₂O-Based Radicals

18 September 2025 by Andrea Orellana Ben Amor and others at

Toulouse

Inorganic Chemistry, Frustrated Lewis Pairs

Olefin Coupling Catalyzed by (Pybox)Os Complexes via Osmacyclopentane Intermediates. Comparison with Isoelectronic (Phebox)Ir

8 September 2025 by Ashish Parihar and others at

American University of Beirut

Organic Chemistry, Catalysis

Electrocatalytic Promiscuity of a Coordinatively Saturated Iron Complex via Ligand Fluxionality and Internal Electric Fields

18 August 2025 by Ayan Santra and others

Inorganic Chemistry, Catalysis

Janus-Faced Reactivity of Heterobimetallic Al–Zn Complexes

4 August 2025 by Jake Hemsworth and others at

University of Manchester

Inorganic Chemistry, Organometallic Chemistry

Ambiphilic Reactivity and Switchable Methyl Transfer at a T-shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand

31 July 2025 by Sotirios Pavlidis and others

Inorganic Chemistry, Main Group Chemistry

Mechanistic insight into cooperative catalysis with pentanuclear nickel clusters: catalytic alkene dimerization and silyl-silylene and silylyne clusters.

24 July 2025 by Junyang Liu and others at

University of Windsor

Organometallic Chemistry, Bond Activation

Reversible room temperature heterolytic activation of vinylic sp2 C–H bonds at a gallium center

15 July 2025 by Kaiyang Liu and others at

UC Los Angeles

Inorganic Chemistry, Main Group Chemistry

Rapid Intermolecular C-H Activation of Aromatic Substrates at a Cationic, Electrophilic Molybdenum (VI) Nitrido Complex: Mechanistic Nuance in C-H Amination

10 July 2025 by C. Christopher Almquist and others at

University of Calgary

Inorganic Chemistry, Coordination Chemistry

General Amidination of Alkenes via Rh-Mediated C–H Activation of Pyridinyl Formimidamide

9 July 2025 by Gaolei Song and others at

Chinese Academy of Sciences

Biological and Medicinal Chemistry, Organic Chemistry

A Crystalline Phosphorus-Substituted Borinium Cation: Double Dihydrogen Activation by an Ambiphilic Inorganic Allene

3 July 2025 by Anna Ordyszewska-Lach and others

Inorganic Chemistry, Frustrated Lewis Pairs

Examining the Oxygen Tolerance of Mn(bpy)(CO)3Br in Electrochemical CO2 Conversion to CO and Formic Acid

27 June 2025 by Catriona James and others at

University of Amsterdam

Inorganic Chemistry, Catalysis

Identifying Reactivity Differences of Two-Carbon-Atom-Based Legacy Refrigerants at Group 9 Metal Pincer Complexes

26 June 2025 by Luc Mauro and others at

Lehigh University

Organic Chemistry, Catalysis

Rapid Nitrite Reduction Enabled by Secondary Sphere Hydrogen Bonds within Non-Heme Iron Complexes

11 June 2025 by Andrew Laduca and others at

Western Washington University

Inorganic Chemistry, Bioinorganic Chemistry

Involvement of Nickel Carbonites in the Formation of Oxalate: a Combined Experimental and Computational Study

6 June 2025 by Siad Wolff and others

Theoretical and Computational Chemistry, Inorganic Chemistry

H2-Eliminating Reductive N2 Binding: a Dinickel-Bridging Bent N2 Radical Anion and its Redox-Triggered N2 Release

3 June 2025 by Sara Ida Mozzi and others

Inorganic Chemistry, Bioinorganic Chemistry

Metal-Ligand Covalency of C-H Activating Iridium Complexes from L-edge Valence-to-Core Resonant Inelastic X-ray Scattering

31 May 2025 by Raphael Jay and others at

Uppsala University

Physical Chemistry, Organometallic Chemistry

Catalytic Ammonia Synthesis via Protonation-Induced Cleavage of a Dinitrogen-Bridged Dimolybdenum Complex with a 𝜋8 Mo2(μ-N2) Core

22 May 2025 by Souvik Mandal and others at

American University of Beirut

Theoretical and Computational Chemistry, Inorganic Chemistry

Bis(Cyclooctadiene)Nickel(0)-Catalyzed Exhaustive C(sp2) and C(sp3)-X Hydrodehalogenation of Pyridines and Arenes Employing Ammonia Borane and Potassium Tert-Butoxide

22 May 2025 by Himani Ahuja and Rebeca Arevalo at

UC Merced

Organic Chemistry, Catalysis

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Articles about Small Molecule Activation