Sign in

Ru-Catalyzed Carbonylative Murai Reaction: Directed C3-Acylation of Biomass-Derived 2-Formyl Heteroaromatics

By Roberto Sala and others
<p>We describe here the carbonylative Murai reaction applied to 2-formylfurans, 2-formylpyrrols and 2-formylthiophenes. Thanks to the installation of removable imine directing groups, this acylation reaction takes place regioselectively at C3 position of the heterocyclopentadienes. It can be achieved by treating the two reaction partners with a catalytic amount of Ru<sub>3</sub>(CO)<sub>12</sub>, in toluene at 120-150 °C, after... Show more
December 17, 2019
=
0
Loading PDF…
Loading full text...
Similar articles
Loading recommendations...
=
0