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Ru(0)-Catalyzed Alkenylation of 2-Carboxaldimine Heterocyclopenta-dienes with H2 Transfer

By Roberto Sala and others at
LogoSorbonne University
A new Ru3(CO)12-catalyzed directed alkenylation of 2-carboxaldimine-heterocyclopentadienes has been accomplished. This process allows to couple furan, pyrrole, indole and thiophene 2-carboxaldimines with electron-poor alkenes such as acrylates, vinylsulfones, and styrenes. This regio- and chemoselective oxidative C–H coupling does not require the presence of an additional sacrificial oxidant. Density functional theory... Show more
November 15, 2021
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