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A Highly Stereoselective Claisen-Sakurai Approach to Densely Functionalized Cyclopentenols

By Matthew Cook and Ksenia Stankevich at
LogoMontana State University
The formation of highly substitiuted cyclopentenols was developed using a Claisen-Sakurai reaction. Both elements of the reaction can be performed in a one-pot sequence that provides the corresponding cyclized products in high stereoselectivity. The stereochemical outcome is defined by a combination of Claisen stereospecificity and stereoelectronic effects in the Sakurai... Show more
May 4, 2022
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