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Postsynthetic Modification Strengthens the Stereoselectively Self-Assembled Hemiaminal Ether Complexes

By Sakthi Raje and others at
LogoIndian Institute of Technology Kanpur
Fragile hemiaminal ether linkages present in the backbone of koneramines (LROR’), potential tridentate ligands, bound to copper(II) in stereoselectively self-assembled syn-[Cu(LROR’)X2] complexes were transformed into sturdy methylene linkages to make corresponding rac-[Cu(LRH)Cl2] complexes by homogeneous postsynthetic modification with the retention of coordination sphere. The generality of stereoselective self-assembly of koneramine... Show more
August 26, 2022
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