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Multi-edge X-ray Absorption Spectroscopic Evidence for Sulphur-based Redox in [4Fe-4S] Molecular Clusters

By Robert Szilagyi at
LogoUniversity of British Columbia
Central to the dogma of Fe–S World Hypothesis for the Emergence of Biosphere is the transition from non-living Fe–S geochemistry to the molecular Fe–S biochemistry. While often assumed this being a trivial and spontaneous process; however, the chemical reality is a critical discontinuity of oxidation states of ferrous iron-based minerals... Show more
July 8, 2024
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Multi-edge X-ray Absorption Spectroscopic Evidence for Sulphur-based Redox in [4Fe-4S] Molecular Clusters
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