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Light-Triggered Rolling and Unrolling of Molecular Crystal Microsheets

By Pranay Ghate and others at
LogoUC Riverside
The anthracene derivative (E)-3-(3-(anthracen-9-yl)allylidene)-1,5-dioxaspiro[5.5]undecane-2,4-dione (E-ADUD) undergoes an EZ photoisomerization in solution but is inactive when crystals are grown using standard methods like solvent diffusion. However, the lipophilic cyclohexyl group facilitates precipitation of crystalline microsheets with submicron thicknesses from an aqueous solution containing sodium dodecyl sulfate and 1-dodecanol. These... Show more
July 9, 2024
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Light-Triggered Rolling and Unrolling of Molecular Crystal Microsheets
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