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Copper-Catalyzed Electrophilic Amination of ArylZinc Pivalates mediated by N-based Hypervalent Iodine(III) Reagents

By Ana Cláudia Negrão and others at
LogoNOVA School of Science and Technology
and
LogoUniversidade Nova de Lisboa
We describe a new Cu-catalyzed electrophilic amination of stable polyfunctional organozinc compounds using new hypervalent iodine reagents bearing transferable alkyl and aryl amines. A wide range of aryl, heteroaryl and alkyl amines were prepared, and the method applied to the synthesis of chloroquine drug. The mechanism of the reaction was... Show more
July 5, 2024
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Copper-Catalyzed Electrophilic Amination of ArylZinc Pivalates mediated by N-based Hypervalent Iodine(III) Reagents
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