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A Versatile and Fast Photocatalyzed Deoxygenation of Organic N-oxides with a Rhenium Complex in the Presence of H2O

By Nicolas Joly and others at
LogoCEA Paris-Saclay
and
LogoCNRS
The oxidation of N-heterocycles is key to their functionalization since it enhances their reactivity in the ortho position. How-ever, an efficient post-reduction is often required to access the targeted compound. Here, a rhenium-based photocatalyst enables the versatile and fast deoxygenation of N-heterocyclic and alkyl N-oxides, avoiding sacrificial oxophilic reagents. The... Show more
July 11, 2024
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A Versatile and Fast Photocatalyzed Deoxygenation of Organic N-oxides with a Rhenium Complex in the Presence of H2O
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